Geography and Environmental Sciences
WU Qian, ZHU Zhaozhou
To investigate the pollution characteristics, health risks, and sources of radioactive nuclides uranium (U) and thorium (Th) in Beidagang Reservoir, their concentrations in the water were determined using solid-phase extraction coupled with inductively coupled plasma mass spectrometry (ICP-MS). The pollution level and health risks posed by U and Th were assessed via the Nemerow composite pollution index method and health risk models, incorporating Monte-Carlo simulations. Finally, pollution source apportionment was conducted using the positive matrix factorization (PMF) model. The results showed that: ① The activity concentrations of U and Th in the water of Beidagang Reservoir were (50.5 ± 16.5) mBq/L and (0.074 ± 0.034) mBq/L, respectively. Concentrations during the dry season were higher than those in the wet season, primarily due to reduced precipitation recharge and enhanced evaporation. ② During the wet season, the probabilities of the water being at clean and relatively clean levels were 3.16% and 96.80%, respectively, with a 0.04% probability of slight pollution. In the dry season, the probability of the water being at clean and relatively clean levels were 0% and 83.50%, while the probabilities of slight and moderate pollution were 16.14% and 0.36%, respectively. ③ The total carcinogenic risk index of U and Th was 13.93 × 10-6, indicating a potential carcinogenic risk. The chemical toxicity hazard quotient was minimal, suggesting that chemical toxicity could be neglected. ④ The pollution source analysis results showed that the main sources of radioactive nuclide U in Beidagang Reservoir were soil, agriculture, marine, and industrial, with contribution rates of 24.6%, 50.8%, 20.9%, and 3.7%, respectively. The main sources of Th were soil, marine, and industrial, with contribution rates of 57.6%, 32.6%, and 9.8%, respectively.